Reductive Dimerization of the Cyclohexadienyl Complex [Mn(CO)3(η5-C6H7)] through a Radical Pathway.

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dc.contributor.author Shao, Li
dc.contributor.author Geib, Steven J.
dc.contributor.author Badger, Paul D.
dc.contributor.author Cooper, N. John
dc.date.accessioned 2020-01-21T18:28:40Z
dc.date.available 2020-01-21T18:28:40Z
dc.date.issued 2003
dc.identifier.citation Shao, L., Geib, S. J., Badger, P. D.,Cooper, N. J. (2003). Reductive Dimerization of the Cyclohexadienyl Complex [Mn(CO)3(η5-C6H7)] through a Radical Pathway American Chemical Society, Organometallics. 22, (20), 3977-3979 en_US
dc.identifier.uri http://hdl.handle.net/11347/329
dc.description.abstract Slow naphthalenide reduction of [Mn(η5-C6H7)(CO)3] (1) generates the transient anionic radical [Mn(η5-C6H7)(CO)3]•- (4•-), which adds as a nucleophile to 1 to form, after further reduction, [Mn(CO)3{η4-C6H7−CO−Mn(η5-C6H7)(CO)2}]2-, while fast reduction of 1 at low temperature gives [{Mn(CO)3}2(μ2-η4:η4-C6H7−C6H7)]2-, a dimer of 4•-. Both reactions suggest that formation of transient 4•- allows access to new reaction manifolds in which the cyclohexadienyl ligand of the classic complex 1 has been activated to further reactions. en_US
dc.language.iso en_US en_US
dc.publisher American Chemical Society, Organometallics en_US
dc.subject Naphthalenide reduction en_US
dc.subject Transient formation en_US
dc.subject Reactions en_US
dc.subject Crystallization en_US
dc.subject Compound en_US
dc.subject Chemical en_US
dc.subject Data processing en_US
dc.title Reductive Dimerization of the Cyclohexadienyl Complex [Mn(CO)3(η5-C6H7)] through a Radical Pathway. en_US
dc.type Article en_US


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